Illustrator: Is there a way to assign “Align to Selection”, “Align to Artboard” etc to a keys or to one key so I can toggle between them?

You can’t do it with Keyboard Shortcuts as it is not a menu item

I want to this as I have assigned the other Align Commands to my WACOM buttons:

I made a complex keyboard shortcut for each of the commands in Illustrator (so I don’t press it accidentally). Then using the WACOM sys pref pane I then just assigned that complex button press to the key that I want. Using different combinations of modifiers I can assign all the keys and select different things using SHIFT.

But I can’t do this with the highlighted items as they don’t appear in the Keyboard Shortcuts menu. I don’t like having to open up that little tag every time I want to change the mode.